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Samarium Polyarsenides Derived from Nanoscale Arsenic

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Harvard

Schoo, C, Bestgen, S, Egeberg, A, Seibert, J, Konchenko, SN, Feldmann, C & Roesky, PW 2019, 'Samarium Polyarsenides Derived from Nanoscale Arsenic' Angewandte Chemie (International ed. in English), vol. 58, no. 13, pp. 4386-4389. https://doi.org/10.1002/anie.201813370

APA

Schoo, C., Bestgen, S., Egeberg, A., Seibert, J., Konchenko, S. N., Feldmann, C., & Roesky, P. W. (2019). Samarium Polyarsenides Derived from Nanoscale Arsenic. Angewandte Chemie (International ed. in English), 58(13), 4386-4389. https://doi.org/10.1002/anie.201813370

CBE

Schoo C, Bestgen S, Egeberg A, Seibert J, Konchenko SN, Feldmann C, Roesky PW. 2019. Samarium Polyarsenides Derived from Nanoscale Arsenic. Angewandte Chemie (International ed. in English). 58(13):4386-4389. https://doi.org/10.1002/anie.201813370

MLA

Vancouver

Schoo C, Bestgen S, Egeberg A, Seibert J, Konchenko SN, Feldmann C et al. Samarium Polyarsenides Derived from Nanoscale Arsenic. Angewandte Chemie (International ed. in English). 2019 Mar 22;58(13):4386-4389. https://doi.org/10.1002/anie.201813370

Author

Schoo, Christoph ; Bestgen, Sebastian ; Egeberg, Alexander ; Seibert, Jasmin ; Konchenko, Sergey N ; Feldmann, Claus ; Roesky, Peter W. / Samarium Polyarsenides Derived from Nanoscale Arsenic. In: Angewandte Chemie (International ed. in English). 2019 ; Vol. 58, No. 13. pp. 4386-4389.

Bibtex

@article{b0d932f68ba545c5919c445df33f41a8,
title = "Samarium Polyarsenides Derived from Nanoscale Arsenic",
abstract = "Zintl phases of arsenic and molecular compounds containing Zintl-type polyarsenide ions are of fundamental interest in basic and applied sciences. Unfortunately, the most obvious and reactive arsenic source for the preparation of defined molecular polyarsenide compounds, yellow arsenic As4 , is very inconvenient to prepare and neither storable in pure form nor easy to handle. Herein, we present the synthesis and reactivity of elemental As0 nanoparticles (As0Nano , d=7.2±1.8 nm), which were successfully utilized as a reactive arsenic source in reductive f-element chemistry. Starting from [Cp*2 Sm] (Cp*=η5 -C5 Me5 ), the samarium polyarsenide complexes [(Cp*2 Sm)2 (μ-η2 :η2 -As2 )] and [(Cp*2 Sm)4 As8 ] were obtained from As0nano , thereby generating the largest molecular polyarsenide of the f-elements and circumventing the use of As4 in preparative chemistry.",
author = "Christoph Schoo and Sebastian Bestgen and Alexander Egeberg and Jasmin Seibert and Konchenko, {Sergey N} and Claus Feldmann and Roesky, {Peter W}",
note = "{\circledC} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2019",
month = "3",
day = "22",
doi = "10.1002/anie.201813370",
language = "English",
volume = "58",
pages = "4386--4389",
journal = "Angewandte Chemie International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH",
number = "13",

}

RIS

TY - JOUR

T1 - Samarium Polyarsenides Derived from Nanoscale Arsenic

AU - Schoo, Christoph

AU - Bestgen, Sebastian

AU - Egeberg, Alexander

AU - Seibert, Jasmin

AU - Konchenko, Sergey N

AU - Feldmann, Claus

AU - Roesky, Peter W

N1 - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2019/3/22

Y1 - 2019/3/22

N2 - Zintl phases of arsenic and molecular compounds containing Zintl-type polyarsenide ions are of fundamental interest in basic and applied sciences. Unfortunately, the most obvious and reactive arsenic source for the preparation of defined molecular polyarsenide compounds, yellow arsenic As4 , is very inconvenient to prepare and neither storable in pure form nor easy to handle. Herein, we present the synthesis and reactivity of elemental As0 nanoparticles (As0Nano , d=7.2±1.8 nm), which were successfully utilized as a reactive arsenic source in reductive f-element chemistry. Starting from [Cp*2 Sm] (Cp*=η5 -C5 Me5 ), the samarium polyarsenide complexes [(Cp*2 Sm)2 (μ-η2 :η2 -As2 )] and [(Cp*2 Sm)4 As8 ] were obtained from As0nano , thereby generating the largest molecular polyarsenide of the f-elements and circumventing the use of As4 in preparative chemistry.

AB - Zintl phases of arsenic and molecular compounds containing Zintl-type polyarsenide ions are of fundamental interest in basic and applied sciences. Unfortunately, the most obvious and reactive arsenic source for the preparation of defined molecular polyarsenide compounds, yellow arsenic As4 , is very inconvenient to prepare and neither storable in pure form nor easy to handle. Herein, we present the synthesis and reactivity of elemental As0 nanoparticles (As0Nano , d=7.2±1.8 nm), which were successfully utilized as a reactive arsenic source in reductive f-element chemistry. Starting from [Cp*2 Sm] (Cp*=η5 -C5 Me5 ), the samarium polyarsenide complexes [(Cp*2 Sm)2 (μ-η2 :η2 -As2 )] and [(Cp*2 Sm)4 As8 ] were obtained from As0nano , thereby generating the largest molecular polyarsenide of the f-elements and circumventing the use of As4 in preparative chemistry.

U2 - 10.1002/anie.201813370

DO - 10.1002/anie.201813370

M3 - Journal article

VL - 58

SP - 4386

EP - 4389

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 13

ER -

ID: 57775411